# -*- coding: utf-8 -*-
# Bioindustrial-Park: BioSTEAM's Premier Biorefinery Models and Results
# Copyright (C) 2021-2024, Yalin Li <mailto.yalin.li@gmail.com>
#
# This module is under the UIUC open-source license. See
# github.com/BioSTEAMDevelopmentGroup/biosteam/blob/master/LICENSE.txt
# for license details.
sympy = None
import biosteam as bst
from . import (
get_BD_dct,
compute_stream_COD,
get_digestion_rxns,
IC_purchase_cost_algorithms
)
__all__ = ('InternalCirculationRx',)
# %%
[docs]
class InternalCirculationRx(bst.MixTank):
"""
Internal circulation (IC) reactor for anaerobic digestion (AD),
including a high-rate bottom reactor for rapid organic removal and
a low-rate top reactor for polishing.
Both reactors are similar to upflow anaerobic blanket reactor (UASB).
Design of the reactor follows steps described in [4]_
(assuming steady state and pseudo-zeroth-order kinetics),
where two methods are used based on Irizar et al. [7]_ and
Tchobanoglous et al. [8]_.
Parameters
----------
ins :
Influent.
outs :
* [0] biogas
* [1] effluent
* [2] waste sludge
method : str
* "separate" to design the bottom and top reactors separately as in [7]_.
Design parameters for this methid include OLRall, biodegradability, Y,
q_Qw, mu_max, b, Fxt, and Fxb.
* "lumped" to design the entire IC reactor as a black box following [8]_.
Design parameters for this method include OLRall, biodegradability, Y,
q_Qw, and q_Xw.
OLRall : float
Overall organic loading rate, [kg COD/m3/hr].
Y_biogas : float
Biogas yield, [kg biogas/kg consumed COD].
Y_biomass : float
Biomass yield, [kg biomass/kg consumed COD].
biodegradability : float or dict
Biodegradability of chemicals,
when shown as a float, all biodegradable chemicals are assumed to have
the same degradability.
q_Qw : float
Ratio between the bottom reactor waste flow and the influent.
q_Xw : float
Ratio between the biomass concentration in the reactor and the waste flow.
mu_max : float
Maximum specific growth rate, [/hr].
b : float
Specific endogenous decay coefficient, [/hr].
V_wf : float
Fraction of working volume over total volume.
vessel_type : str
Can be "IC" to use the reactor size constraints according to [4]_,
or "Conventional" based on :class:`biosteam.MixTank`
(much smaller tank size, not recommended).
vessel_material : str
Vessel material.
kW_per_m3 : float
Electricity requirement per unit volume, [kW/m^3].
Default to 0 as IC reactors realizes mixing through internal circulation
caused by the rising force of the generated biogas.
T : float
Temperature of the reactor.
Will not control temperature if provided as None.
kwargs : dict
Other keyword arguments (e.g., Fxb, Fxt).
"""
_N_ins = 1
_N_outs = 3 # biogas, effluent, waste sludge
# Assumptions
_q_Qw = 0.01
_q_Xw = 1.5
_mu_max = 0.01
_b = 0.00083
_Fxb = 0.0032
_Fxt = 0.0281
_Y = 0.05
# Related to cost algorithm
_default_vessel_type = 'IC'
_default_vessel_material = 'Stainless steel'
purchase_cost_algorithms = IC_purchase_cost_algorithms
# Other equipment
auxiliary_unit_names = ('heat_exchanger', 'effluent_pump', 'sludge_pump')
def _init(self, method='lumped', OLRall=1.25, Y_biogas=0.86, Y_biomass=0.05, biodegradability={},
vessel_type='IC', vessel_material='Stainless steel',
V_wf=0.8, kW_per_m3=0., T=35+273.15, hxn_ok=False, **kwargs):
self.method = method
self.OLRall = OLRall
self.Y_biogas = Y_biogas
self.Y_biomass = Y_biomass
self.biodegradability = \
biodegradability if biodegradability else get_BD_dct(self.chemicals)
self.V_wf = V_wf or self._default_V_wf
self.vessel_type = 'IC'
self.vessel_material = vessel_material
self.kW_per_m3 = kW_per_m3
self.T = T
# Initialize the attributes
ID = self.ID
self._inf = bst.Stream(f'{ID}_inf')
hx_in = bst.Stream(f'{ID}_hx_in')
hx_out = bst.Stream(f'{ID}_hx_out')
# Add '.' in ID for auxiliary units
self.heat_exchanger = bst.HXutility(ID=f'.{ID}_hx', ins=hx_in, outs=hx_out, T=T)
self._refresh_rxns()
# Conversion will be adjusted in the _run function
self._decay_rxn = self.chemicals.WWTsludge.get_combustion_reaction(conversion=0.)
self.effluent_pump = bst.Pump(f'.{ID}_eff', ins=self.outs[1].proxy(f'{ID}_eff'))
self.sludge_pump = bst.Pump(f'.{ID}_sludge', ins=self.outs[2].proxy(f'{ID}_sludge'))
self.hxn_ok = hxn_ok
for k, v in kwargs.items(): setattr(self, k, v)
def _refresh_rxns(self, Y_biogas=None, Y_biomass=None):
Y_biogas = Y_biogas if Y_biogas else self.Y_biogas
Y_biomass = Y_biomass if Y_biomass else self.Y_biomass
self._biogas_rxns = get_digestion_rxns(self.ins[0], self.biodegradability,
Y_biogas, 0., 'WWTsludge')
self._growth_rxns = get_digestion_rxns(self.ins[0], self.biodegradability,
0., Y_biomass, 'WWTsludge')
self._i_rm = self._biogas_rxns.X + self._growth_rxns.X
@staticmethod
def _degassing(original_stream, receiving_stream):
gases = tuple(i.ID for i in original_stream.chemicals if i.locked_state=='g')
receiving_stream.imass[gases] += original_stream.imass[gases]
original_stream.imass[gases] = 0
@staticmethod
def compute_COD(stream):
r"""
Compute the chemical oxygen demand (COD) of a given stream in kg-O2/m3
by summing the COD of each chemical in the stream using:
.. math::
COD [\frac{kg}{m^3}] = mol_{chemical} [\frac{kmol}{m^3}] * \frac{g O_2}{mol\ chemical}
"""
return compute_stream_COD(stream)
def _run(self):
inf = self._inf
inf.copy_like(self.ins[0])
biogas, eff, waste = self.outs
degassing = self._degassing
# Initialize the streams
biogas.phase = 'g'
biogas.empty()
inf.split_to(waste, eff, self.q_Qw)
biogas_rxns = self.biogas_rxns
growth_rxns = self.growth_rxns
growth_rxns(inf.mol)
biogas_rxns(inf.mol)
degassing(inf, biogas)
Se = self.compute_COD(inf)
Qi, Si, Xi, Qe, Y = self.Qi, self.Si, self.Xi, self.Qe, self.Y_biomass
method = self.method.lower()
if method == 'separate':
run_inputs = (Qi, Si, Xi, Qe, Se, self.Vliq, Y,
self.mu_max, self.b, self.Fxb, self.Fxt)
Xw, Xe = self._run_separate(run_inputs)
else:
Xe = (Qi*Xi+Qi*(Si-Se)*Y)/(Qe+(Qi-Qe)*self.q_Xw)
Xw = Xe * self.q_Xw
for rxns in (growth_rxns, biogas_rxns):
rxns(waste.mol)
rxns(eff.mol)
degassing(eff, biogas)
degassing(waste, biogas)
eff.imass['WWTsludge'] = Xe*self.Qe
waste.imass['WWTsludge'] = Xw*self.Qw
diff = sum(i.imol['WWTsludge'] for i in self.outs) - inf.imol['WWTsludge']
if diff > 0:
decay_rxn = self.decay_rxn
decay_rxn._X = min(1., diff / inf.imol['WWTsludge'])
for i in (eff, waste):
decay_rxn.force_reaction(i.mol)
i.imol['O2'] = max(0, i.imol['O2'])
degassing(i, biogas)
if self.T: biogas.T = eff.T = waste.T = self.T
def _run_separate(self, run_inputs):
global sympy
if sympy is None: import sympy
Qi, Si, Xi, Qe, Se, Vliq, Y, mu_max, b, Fxb, Fxt = run_inputs
Qw = Qi - Qe
Xb, Xe, Sb, Vb = sympy.symbols('Xb, Xe, Sb, Vb', real=True)
# Mass balances based on biomass/substrate changes in the bottom/top rx,
# (0 at steady state)
biomass_b = Qi*Xi - (Qe*Xb*Fxb+Qw*Xb) + Xb*Vb*(mu_max-b)
biomass_t = Qe*(Fxb*Xb-Fxt*Xe) + Xe*(Vliq-Vb)*(mu_max-b)
substrate_b = Qi*(Si-Sb) - mu_max*(Xb*Vb/Y)
substrate_t = Qe*(Sb-Se) - mu_max*((Vliq-Vb)*Xe/Y)
parameters = (Qi, Qe, Si, Se, Vliq)
results = sympy.solve(
(sympy.Eq(biomass_b, 0),
sympy.Eq(biomass_t, 0),
sympy.Eq(substrate_b, 0),
sympy.Eq(substrate_t, 0)), (Xb, Xe, Sb, Vb))
Xb, Xe, Sb, Vb = self._filter_results('separate', parameters, results)
Vt = Vliq - Vb # volume of the top rx, m3
self._Vb, self._Vt = Vb, Vt
return Xb, Xe
@staticmethod
def _filter_results(method, parameters, results):
"""Check if the solution satisfies the design constraints."""
Qi, Qe, Si, Se, Vliq = parameters
solutions = []
for result in results:
Xb, Xe, Sb, Vb = result
Vt = Vliq - Vb
OLRt = Qe*Sb / Vt
OLRb = Qi*Si / Vb
if (
0 <= OLRt <= OLRb and
0 <= Se <= Sb <= Si and
0 <= Xe <= Xb and
0 <= Vb <= Vliq
):
solutions.append(result)
if len(solutions) == 0 :
raise bst.DesignError('No feasible design found for the given parameters.')
elif len(solutions) >1: # find more than one solution
Xbs = [i[1] for i in solutions]
index = Xbs.index(min(Xbs)) # choose the one with lowest effluent biomass
return solutions[index]
_units = {
'HRT': 'hr',
'SRT': 'hr',
'Single reactor liquid volume': 'm3',
'Bottom reactor volume': 'm3',
'Top reactor volume': 'm3',
'Gas chamber volume': 'm3'
}
def _design(self):
D = self.design_results
D['HRT'] = D['Residence time'] = self.HRT
D['SRT'] = self.SRT
D['Total volume'] = self.Vtot
D['Total liquid volume'] = self.Vliq
if self.method == 'separate':
D['Bottom reactor volume'] = self.Vb
D['Top reactor volume'] = self.Vt
def _cost(self):
bst.MixTank._cost(self)
hx = self.heat_exchanger
ins0 = self.ins[0]
hx.ins[0].copy_flow(ins0)
hx.outs[0].copy_flow(ins0)
hx.ins[0].T = ins0.T
hx.outs[0].T = self.T
hx.ins[0].P = hx.outs[0].P = ins0.P
hx.simulate_as_auxiliary_exchanger(ins=hx.ins, outs=hx.outs,
scale=1. / self.parallel.get('self', 1.),
vle=False,
hxn_ok=self.hxn_ok)
for p in (self.effluent_pump, self.sludge_pump): p.simulate()
@property
def method(self):
"""[str] Design method, can be "separate" or "lumped"."""
return self._method
@method.setter
def method(self, i):
if not i.lower() in ('separate', 'lumped'):
raise ValueError('`method` can only be "separated", or "lumped", '
f'not "{i}".')
self._method = i.lower()
@property
def OLRall(self):
"""[float] Overall organic loading rate, [kg COD/m3/hr]."""
return self._OLRall
@OLRall.setter
def OLRall(self, i):
if i < 0:
raise ValueError('`OLRall` should be >=0, '
f'the input value {i} is outside the range.')
self._OLRall = i
@property
def biodegradability(self):
"""
[float of dict] Biodegradability of chemicals,
when shown as a float, all biodegradable chemicals are assumed to have
the same degradability.
"""
return self._biodegradability
@biodegradability.setter
def biodegradability(self, i):
if not isinstance(i, dict):
if not 0<=i<=1:
raise ValueError('`biodegradability` should be within [0, 1], '
f'the input value {i} is outside the range.')
self._biodegradability = dict.fromkeys(self.chemicals.IDs, i)
else:
for k, v in i.items():
if not 0<=v<=1:
raise ValueError('`biodegradability` should be within [0, 1], '
f'the input value for chemical "{k}" is '
'outside the range.')
self._biodegradability = dict.fromkeys(self.chemicals.IDs, i).update(i)
self._refresh_rxns()
@property
def i_rm(self):
"""[:class:`np.array`] Removal of each chemical in this reactor."""
return self._i_rm
@property
def q_Qw(self):
"""[float] Ratio between the bottom reactor waste flow and the influent."""
return self._q_Qw
@q_Qw.setter
def q_Qw(self, i):
if not 0<=i<=1:
raise ValueError('`q_Qw` should be within [0, 1], '
f'the input value {i} is outside the range.')
self._q_Qw = i
@property
def q_Xw(self):
"""
[float] Ratio between the biomass concentration in the reactor and the waste flow,
only relevant when the "lumped" method is used.
"""
return self._q_Xw if self.method=='lumped' else None
@q_Xw.setter
def q_Xw(self, i):
if not i>=1:
raise ValueError('`q_Xw` should be >=1, '
f'the input value {i} is outside the range.')
self._q_Xw = i
@property
def mu_max(self):
"""
[float] Maximum specific growth rate, [/hr],
only relevant when the "separate" method is used.
"""
return self._mu_max if self.method=='separate' else None
@mu_max.setter
def mu_max(self, i):
if i < 0:
raise ValueError('`mu_max` should be >= 0, '
f'the input value {i} is outside the range.')
self._mu_max = i
@property
def b(self):
"""
[float] Specific endogenous decay coefficient, [/hr],
only relevant when the "separate" method is used.
"""
return self._b if self.method=='separate' else None
@b.setter
def b(self, i):
if i < 0:
raise ValueError('`b` should be >= 0, '
f'the input value {i} is outside the range.')
self._b = i
@property
def Fxb(self):
"""
[float] Biomass transfer ratio from the bottom reactor to the top reactor,
should be within [0, 1] (ideal to no retention),
only relevant when the "separate" method is used.
"""
return self._Fxb if self.method=='separate' else None
@Fxb.setter
def Fxb(self, i):
if not 0<=i<=1:
raise ValueError('`Fxb` should be within [0, 1], '
f'the input value {i} is outside the range.')
self._Fxb = i
@property
def Fxt(self):
"""
[float] Biomass transfer ratio from the top reactor to the effluent,
should be within [0, 1] (ideal to no retention),
only relevant when the "separate" method is used.
"""
return self._Fxt if self.method=='separate' else None
@Fxt.setter
def Fxt(self, i):
if not 0<=i<=1:
raise ValueError('`Fxt` should be within [0, 1], '
f'the input value {i} is outside the range.')
self._Fxt = i
@property
def Vb(self):
"""
[float] Volume of the bottom reactor, [m3],
only relevant when the "separate" method is used.
"""
return self._Vb if self.method=='separate' else None
@property
def Vt(self):
"""
[float] Volume of the top reactor, [m3],
only relevant when the "separate" method is used.
"""
return self._Vt if self.method=='separate' else None
@property
def Vliq(self):
"""
[float] Total volume of the liquid, not considering gas headspace
and `V_wf`, [m3].
"""
return self.Qi*self.Si / self.OLRall
@property
def Vtot(self):
"""
[float] Total volume considering `V_wf`, [m3].
"""
return self.Vliq / self.V_wf
@property
def HRT(self):
"""[float] Hydraulic retention time [hr]."""
return self.Vliq / self.Qi
@property
def tau(self):
"""
[float] Reactor residence time, [hr]
(same as the hydraulic retention time, HRT).
"""
return self.HRT
@property
def SRT(self):
"""[float] Solid residence time [hr]."""
if self.method == 'separate':
return (self.Xb*self.Vb+self.Xe*self.Vt)/(self.q_Qw*self.Xb+self.Fxt*self.Qe*self.Xe)
return self.Xe*self.Vliq / (self.q_Qw*self.q_Xw+self.Qe*self.Xe)
@property
def biogas_rxns(self):
"""
[:class:`tmo.ParallelReaction`] Biogas production reactions.
"""
return self._biogas_rxns
@property
def growth_rxns(self):
"""
[:class:`tmo.ParallelReaction`] Biomass (WWTsludge) growth reactions.
"""
return self._growth_rxns
@property
def decay_rxn(self):
"""
[:class:`tmo.Reaction`] Biomass endogenous decay.
.. note::
Conversion is adjusted in the _run function.
"""
return self._decay_rxn
@property
def Qi(self):
"""[float] Influent volumetric flow rate, [m3/hr]."""
return self.ins[0].F_vol
@property
def Qe(self):
"""[float] Effluent volumetric flow rate, [m3/hr]."""
return self.outs[1].F_vol
@property
def Qw(self):
"""[float] Waste flow volumetric flow rate, [m3/hr]."""
return self.outs[2].F_vol
@property
def Si(self):
"""
[float] Influent substrate (i.e., biodegradable chemicals)
concentration, [kg/m3].
"""
return self.compute_COD(self.ins[0])
@property
def Se(self):
"""
[float] Effluent substrate (i.e., biodegradable chemicals)
concentration, [kg/m3].
"""
return self.compute_COD(self.outs[1])
@property
def Sw(self):
"""
[float] Waste flow substrate (i.e., biodegradable chemicals)
concentration, [kg/m3].
"""
return self.compute_COD(self.outs[2])
@property
def Xi(self):
"""[float] Influent biomass (i.e., `WWTsludge`) concentration, [kg/m3]."""
return self.ins[0].imass['WWTsludge']/self.ins[0].F_vol
@property
def Xe(self):
"""[float] Effluent biomass (i.e., `WWTsludge`) concentration, [kg/m3]."""
return self.outs[1].imass['WWTsludge']/self.outs[1].F_vol
@property
def Xw(self):
"""[float] Waste flow biomass (i.e., `WWTsludge`) concentration, [kg/m3]."""
return self.outs[2].imass['WWTsludge']/self.outs[2].F_vol
@property
def organic_rm(self):
"""[float] Overall organic (COD) removal rate."""
return 1 - self.Qe*self.Se/(self.Qi*self.Si)
